AProhor                                              

Dr. Anton Prokhorov

Lecturer - Researcher

Ural State Technical University,

Department of Organic Chemistry,

19, Mira-st, K-2

620002, Ekaterinburg, Russia

Birthday: 23.06.1979

E-mail:  aprohor1 @  yandex . ru  (type without space)   

CV in PDF format (65 KB)

Scientific interests:

N-Heterocyclic synthetic chemistry, metalocomplexes, azaheterocyclic ligands, linear and cyclic tetraamine chemistry, magnetic properties, MRI-chemistry, crystal growing. See structures example illustrating my work (images and .cif files).

Education:

• 21 May, 2004: Defense of Ph.D. thesis.

• 6/2001 - 5/2004: Ph.D. Fellowship: Organic Chemistry, Urals State Technical University, Russia. Advisor: Prof. V. Rusinov

• 19 April, 2001: became Diploma-Engineer (Biotechnology)

• 7/1996 - 4/2001: Undergraduate course: Chemical Engineering Faculty, Urals State Technical University, Russia

Research Experience:

• 5/2009 - 7/2009: Professeur Invité in Université de Bretagne Occidentale, France.

• 9/2006 - present: Lecturer. Ural State Technical University, Russia.

• 8/2008 - 9/2008: Short Research Fellowship in frame of Russian Foundation for Basic Research Program: Université de Bretagne Occidentale, France. “Linear and cyclic tetraamine synthesis for medical imaging” Advisor: Prof. Henri Handel 

• 6/2008 - 7/2008: Short Research Fellowship in frame of Russian Foundation for Basic Research Program: University of York, UK. "Triazine Synthesis for Liquide Crystals Materials". Prof. Duncan Bruce.

• 2/2007 - 4/2007: Research Fellowship in frame of Royal Chemical Society Short Visits Program: University of York, United Kingdom. "Triazines synthesis and their transformation into pyridines". Prof. R.J.K.Taylor.

• 7/2006 –  8/2006 : Research Fellow. Ural State Technical University, Russia.

• 6/2005 – 6/2006: Postdoc Fellowship: Université de Bretagne Occidentale, France. “Linear and cyclic tetraamine synthesis for medical imaging” Advisor: Prof. Henri Handel 

• 9/2005 – 5/2006: Research Fellowship: Ural State Technical University, Russia. “Functionalized bipyridines and their azaanalogs synthesis. Metal complexation studies.” Advisor: Prof. Dmitry Kozhevnikov 

• 7/2004 – 9/2004: INTAS Fellowship (YSF 2002-103): Institut für Organische Chemie, Universitaet Regensburg, Germany. “Synthesis of europium bipyridine complexes for peptide labeling.” Advisor: Prof. Burkhard Koenig

•  7/2001 - 5/2004: Ph.D. research: Urals State Technical University, Russia, “Nucleophilic aromatic substitution of hydrogen in azine-N-oxides series with metalorganic reagents as effective method for functionalization of azines and convenient route to new bi -and terpyridine ligands.” Advisor: Prof. Vladimir  Rusinov.

•  5/2003 - 8/2003: Research Fellowship: Institute of Organic Chemistry, Polish Academy of Science, Warsaw. “Direct introduction of acetylene moieties into azines by reactions of nucleophilic substitution of hydrogen.” Advisor: Prof. Mieczyslaw Makosza.

•  2/2003 - 4/2003: INTAS Fellowship (YSF 2002-103): Institut für Organische Chemie, Universitaet Regensburg, Germany. “Synthesis of new bipyridine ligands.” Advisor: Prof. Burkhard Koenig

•  8/1998 - 4/2001: Undergraduate Research: Urals State Technical University, Russia. Advisor: The new method for synthesis of 1,2,4-triazine-4-oxides. Advisor: Dmitry Kozhevnikov.

Awards and Grants:

• 2008: Travel grant of Russian Foundation for Basic Research (for participation in “23 International Conference on Organometallic Chemistry”, July 2008, France.

•  2008: Research grant of Russian Foundation for Basic Research (№ 08-03-00585-а).

•  2007: Research grant of Royal Society in frame of Short Visits Program

•  2006: Two-year Grant of President of Russian Federation for young researchers (№ МК-5007.2006).

• 2004: Conference grant of Organizing Committee of III Euchem Conference on Nitrogen Ligands, Camerino, 2004

• 2002-2004: INTAS Young Scientist Fellowship, cat. “B” (YSF №2002-103).

• 2003-2004: President of Russian Federation Scholarship

• 2002: Governor of Ekaterinburg region Scholarship

• 2001: Soros student

Publication:

1. Anton M. Prokhorov, Mieczysław Mąkosza, Oleg N. Chupakhin. Direct introduction of the acetylene moieties into azines by SNH methodology. Tetrahedron Lett., 2009, 50, 1444-1446.

2. Anton M. Prokhorov, Pavel A. Slepukhin, Vladimir L. Rusinov, Valery N. Kalinin, Dmitry N. Kozhevnikov. 9-Allyl-1,7-dicarbadodecaborane as a dienophile in aza Diels–Alder reactions of 1,2,4-triazines: synthesis of pyridines bearing a carborane cage. Tetrahedron Lett., 2008, 49, 3785-3789.

3. A.M. Prokhorov, D.N. Kozhevnikov, V.L. Rusinov, O.N. Chupakhin, G.G. Aleksandrov, Y. N. Shvachko, D. V. Starichenko, A. V. Korolev, D. V. Bukhvalov, V. V. Ustinov. Influence of π-stacking on magnetic properties in Cu(II) complexes of 3-(2-pyridyl)-5-trifluoroacetylmethyl-1,2,4-triazines. Rus. Chem. Bull., 2008, № 3, 549-554.

4.  Anton Prokhorov,  Hélène Bernard, Nathalie Le Bris, Nicolas Marquet, Henri Handel. Synthesis of a New Ditopic Ligand Possessing Linear and Cyclic Tetraaza Subunits. Synth, Comm., 2008, 38, 1589-1600.

5. Anton M. Prokhorov, Pavel A. Slepukhin, Dmitry N. Kozhevnikov. CuCl2 induced reactions of 6-ethynyl- and 6-cyano-5-aryl-2,2′-bipyridines with various N- and O-nucleophiles in comparison with the reactions of relative 1,2,4-triazines. J. Organomet. Chem., 2008, 693, 1886-1894.

6. Anton Prokhorov, Nathalie Le Bris, Hélène Bernard, Géraldine Claudon, Henri Handel. Cyclohexanedione Bisaminals as Intermediates for Cyclen, Homocyclen, and Cyclam Synthesis. Synthetic Comm., 2006, 36 (21), 3271-3282.

7. Anton M. Prokhorov, Dmitry N. Kozhevnikov, Vladimir L. Rusinov, Oleg N. Chupakhin, Ivan V. Glukhov, Mikhail Yu. Antipin, Olga N. Kazheva, Anatolii N. Chekhlov, and Oleg A. Dyachenko. Carborane-Functionalized Polyaza Aromatic Ligands: Synthesis, Crystal Structure, and a Copper(II) Complex.     Organometallics, 2006, 25, 2972-2977.

8. D. N. Kozhevnikov, V. N. Kozhevnikov, A. M. Prokhorov, M. M. Ustinova, V. L. Rusinov, O. N. Chupakhin. Consecutive nucleophilic substitution and aza Diels-Alder reaction – an efficient strategy to functionalized 2,2′-bipyridines. Tetrahedron Lett. 2006, 47, 869–872.

9.  A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, A. I. Matern, M. M. Nikitin, O. N. Chupakhin, I. L. Eremenko, G. G. Aleksandrov. 5-Acylmethyl-3-(2-pyridyl)-1,2,4-triazines: Synthesis and Complexes with Cu(II). Rus. J. Org. Chem., 2005, 41 (11), 1702-1705.

10. O. N. Chupakhin, A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, I. A. Glukhov, Z. A. Starikova, V. A. Ol"shevskaya, V. N. Kalinin, M. Yu. Antipin. Lithiacarboranes and 1,2,4-triazine 4-oxides: SNH reactions and ring transformations. Russ. Chem. Bull., 2004, 1223-1231.

11. D. N. Kozhevnikov, A. M. Prokhorov, V. L. Rusinov, O.N. Chupakhin. Regioselectivity of nucleophilic attack in the reactions of 1,2,4-triazine-4-oxides with some C-nucleophiles. Chemistry of Heterocyclic Compounds, 2004, 40, 911.

12. O.N. Chupakhin, A.M. Prokhorov, D.N. Kozhevnikov, V.L. Rusinov, V.N. Kalinin, V.A. Olshevskaya, I.V. Glukhov. M.Yu. Antipin. 1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane. Mendeleev Communications. 2003, 165-167.

13. A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, O. N. Chupakhin, Aromatic nucleophilic substitution in 1,2,4-triazine 4-oxides with Grignard reagents. Polish J. Chem., 2003, 1157-1161.

14. D. N. Kozhevnikov; I. S. Kovalev; A. M. Prokhorov; V. L. Rusinov; O. N. Chupakhin. S_N^H reactions of pyrazine N-oxides and 1,2,4-triazine 4-oxides with CH-active compounds, Russ. Chem. Bul., 2003, 52, 1588-1594.

15. A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, and O. N. Chupakhin. Nucleophilic substitution or dipolar 1,3-cycloaddition in reactions of cyanamide with 4-arylpyrimidine 1-oxides, Russ. Chem. Bull., 2003, 1195-1197

16. V.N. Kozhevnikov, A.M. Prokhorov, D.N. Kozhevnikov, V.L. Rusinov, O.N. Chupakhin. Direct introduction of cyanamide in triazine cycle. Russ. Chem. Bull. 2000, 1122-1124

17. O.N. Chupakhin, V.N. Kozhevnikov, A.M. Prokhorov, D.N. Kozhevnikov, V.L. Rusinov, The amidine rearrangement in 5-amino-6-aryl-1,2,4-triazine 4-oxides initiated by hydroxylamine, Tetrahedron Lett., 2000, 41, 7379-7382.

18. D. N. Kozhevnikov, A. M. Prokhorov, V. L. Rusinov, O. N. Chupakhin, Auto-aromatization of the s^H-adducts of 1,2,4-triazine 4-oxides with carbanions in reactions of nucleophilic substitution of hydrogen, Mendeleev Communications., 2000, 227-228.

You could see images of some structures I had synthesized and grown crystals for X-ray analysis.

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Unscientific interest:

 Travels by car. Description of voyages from Asia to Europe, TransEurope journey and others see here (in russian)

 

 Drawing :)))

Modified: 18.06.2009