Anton Prokhorov's   Structures

• X-rays of  HeteroarylCarboranes

• X-rays of  Triazine and Bipyrydine Metalocomplexes

• X-rays of  Cyclic and Linear Polyamines

• Laboratories perfomed X-ray analysis

• Publications

Synthesis of all these substances, starting ligands and  their metallocomplexes, as well their crystal growing were perfomed by Dr. Anton Prokhorov. X-ray analyses were perfomed by different laboratories (see footnote).  Cif-file are available for most of the structures (click on the x-ray structure image).

Contact E-mail:      aprohor1    @    yandex.    ru  (please, type without space)

Heteroaryl- Carboranes Structures (synthesized in Prof. D.Kozhevnikov Lab, X-ray studies were perfomed by I.V. Glukhov):

AP460          AP488     

 AP438             AP-D-005

AP471            AP440   

AP448             AP472              

AP449    

Metalocomplexes structures (synthesized in Prof. D.Kozhevnikov Lab, X-ray studies were perfomed by G.G. Alexandrov, except AP614):

 AP412Cu                              

AP545                               

AP537Cu                      

AP551Cu           

AP614^*       

AP558                              

AP570                                            

AP608                            

Cyclic and linear Polyamines (synthesized in Prof. H.Handel Lab (Fance), X-ray studies were perfomed by F. Michaud):

AP-F-11                                   

AP-F-59        

AP-F-52                    

AP-F-55                

Laboratories:

 1.  Ivan V. Glukhov (X-Ray Structural Centre, Chemistry and Material Sciences Division Russian Academy of Sciences)

 2.  Grigory G. Alekandrov (Institute of General and Inorganic Chemistry, Moscow, Russia)

*3.  Olga N. Kazheva (Institute of Problem of Chemical Physics, X-ray crystallography laboratory)

 4.  F. Michaud, (Service commun d'analyse par diffraction des rayons , Universite de Bretagne Occidentale, France)

Publications:

1. D.N. Kozhevnikov, V.N. Kozhevnikov, A.M. Prokhorov, M.M. Ustinova, V.L. Rusinov, O.N. Chupakhin, G.G. Aleksandrov and B. König. Consecutive nucleophilic substitution and aza Diels–Alder reaction—an efficient strategy to functionalized 2,2′-bipyridines. Tetrahedron Lett., 2006, 47, 869-872

2. A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, A. I. Matern, M. M. Nikitin, O. N. Chupakhin, I. L. Eremenko, G. G. Aleksandrov. 5-Acylmethyl-3-(2-pyridyl)-1,2,4-triazines: Synthesis and Complexes with Cu(II). Rus. J. Org. Chem., 2005, 41 (11), 1702-1705

3. O. N. Chupakhin, A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, I. A. Glukhov, Z. A. Starikova, V. A. Ol"shevskaya, V. N. Kalinin, M. Yu. Antipin. Lithiacarboranes and 1,2,4-triazine 4-oxides: S NH reactions and ring transformations. Russ. Chem. Bull. ,2004, 1223-1231

4. O.N. Chupakhin, A.M. Prokhorov, D.N. Kozhevnikov, V.L. Rusinov, V.N. Kalinin, V.A. Olshevskaya, I.V. Glukhov. M.Yu. Antipin. 1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane. Mendeleev Communications,  2003, 165-167

The page was modified: 12.03.2006